Lebostein: I have never understood that...
I guess you really need to think deep enough to understand.
In the first instance, a soundtrack is a DLC. That means the base game is usually required, and if that base game is only Windows, then yes you can say it is kind of Windows Only, though the files themselves, even the downloads (zip files) are suitable for use out-of-the-box with any common OS.
Whatever the state, it is likely determined by the publisher or developer and not GOG.
If you don't have the base game for a soundtrack DLC, then that would require GOG to create a non game entry in your library just for that soundtrack, and that just complicates things I guess. Sometimes we get soundtracks as a free goodies pack, and they get an entry in our personal GOG library. In any case, it requires more work by GOG and permission from the game provider, and I guess GOG have enough on their plate.
Most soundtracks are available from sites like Bandcamp and Soundcloud etc ... usually for a fee of course, just like GOG. GOG's main business is games, and game extras like soundtracks are a kind of bonus.
You should also consider, that soundtracks are often very cheap at GOG unlike other sites that specifically sell music, that is because they want you to buy the game at GOG, not just the soundtrack ... it's a promotional discount thing.